Pressure-Temperature quantification of continental crustal hydration - Colorado Plateau
Data acquired in collaboration with the University of Boulder in Colorado (U.S.A.) for the understanding of the Colorado Plateau elevation. These data sets include mineralogical, petrological, chemical, pressure-temperature modelisation and density evolution.
Crystal structure of di-[mu]-iodido-bis[bis(acetonitrile-[kappa]N)copper(I)]
The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu...Cu distance = 2.7482 (11) Å], the CuI atoms of which are further coordinated by four molecules of acetonitrile. The CuI atom has an overall distorted tetrahedral coordination environment evidenced by L-Cu-L angles (L ...
Crystal structure of di-[mu]-iodido-bis[(dimethyl sulfoxide-[kappa]O)(triphenylphosphane-[kappa]P)copper(I)]
The centrosymmetric dinuclear title compound, [Cu2I2(C2H6OS)2(C18H15P)2], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated CuI atoms are bridged by two [mu]2-iodido ligands in an almost symmetrical ...
Redetermination of the crystal structure of tetrammineplatinum(II) dichloride – A microporous hydrogen-bonded 3D network exhibiting a temperature-dependent order-disorder phase transition
The title compound [Pt(NH3)4]Cl2 (1), prepared by reaction of (NH4)2[PtCl4] with an excess of NH3 in aqueous solution, was crystallized from water and its structure redetermined by single-crystal X-ray diffraction at four different temperatures in the range from 273 K down to 100 K. 1 is composed of ...
Heterodinuclear Diphosphane-Bridged Iron–Platinum Diyne Complexes as Metalloligands for the Assembly of Polymetallic Systems (Fe, Pt, Co)
Treatment of [(OC)3Fe(μ-C=O)(µ-dppm)Pt(PPh3)] (1a) (dppm=Ph2PCH2PPh2) with 1,7-octadiyne affords the isomeric dimetallacyclopentenones [(OC)2Fe(µ-dppm)(µ-C(=O)C{(CH2)4C≡CH}=CH)Pt(PPh3)] (2a) and [(OC)2Fe(µ-dppm)(µ-C(=O)C(H)=C{(CH2)4C≡CH})Pt(PPh3)] (2a′). In a similar manner, the reaction with ...
Interactions of pharmaceutical companies with world countries, cancers and rare diseases from Wikipedia network analysis
Using the English Wikipedia network of more than 5 million articles we analyze interactions and interlinks between the 34 largest pharmaceutical companies, 195 world countries, 47 rare renal diseases and 37 types of cancer. The recently developed algorithm of reduced Google matrix (REGOMAX) allows ...
Population genetics in a mixed maternity colony of Myotis myotis and M. blythii - Bourg d'Oisans
Individual genotypes from 210 samples arising from 165 individuals of a maternity roost located in Le Bourg d'Oisans (French Alps), hosting Myotis myotis and Myotis blythii individuals. Num = sample identifier, ID = individual identifier, Sampling = Sampling date, Type = bat type (Myotis myotis, ...
Crystal structure of tricarbonyl([mu]-diphenylphosphido-[kappa]2P:P)(methyldiphenylsilyl-[kappa]Si)bis(triphenylphosphane-[kappa]P)iron(II)platinum(0)(Fe-Pt)
The title compound, [FePt(C12H10P)(C13H13Si)(C18H15P)2(CO)3]·0.5CH2Cl2, represents an example of a phosphido-bridged heterobimetallic silyl complex; these are interesting precursors for the coordination and activation of small unsaturated organic molecules. The [mu]2-PPh2 ligand spans the iron and ...
Bis{(4-methylthio)phenylthio}methane as assembling ligand for the construction of Cu(I) and Hg(II) coordination polymers. Crystal structures and topological (AIM) analysis of the bonding
The novel 1D coordination polymer (CP) [{Cu(μ2-Br)2Cu}(μ-L2)2] CP2 has been obtained by reaction of the tetrakisthioether p-MeSC6H4SCH2SC6H4SMe-p (L2) with CuBr in a 1:2 metal-to ligand ratio. In contrast to the previously described CP [{Cu(μ2-Br)2Cu}(μ-L1)2] CP1 obtained by reaction of the ...
2-(2,2-Dibromoethenyl)thiophene
The title compound, C6H4Br2S, represents a versatile building block for the preparation of [pi]-conjugated redox-active thienyl oligomers and metal-mediated cross-coupling reactions. This is due to the presence of an electrochemically active thienyl heterocycle and a reactive dibromovinyl ...
Two-dimensional polymeric [Hg4([mu]2-I)6I2([mu]2-C4S6)]n
The title compound, poly[([mu]2-2H,5H-1,3-dithiolo[4,5-d][1,3]dithiole-2,5-dithione)hexa-[mu]2-iodido-diiodidotetramercury(II)], [Hg4I8(C4S6)]n, represents the first example of a coordination polymer assembled by the [alpha],[alpha]-C4S6 dithione ligand. The HgII ions are four-coordinated in a ...
[μ-Bis(diphenylphosphanyl)methane]-tricarbonyl(μ-p-toluenesulfonylmethylisocyanato)(triphenylphosphane)iron-platinum(Fe-Pt)
The title compound, [FePt(C9H9NO2S)(C18H15P)(C25H22P2)(CO)3], represents a rare example of an isonitrile-bridged heterobimetallic complex (here Pt and Fe) and is an interesting precursor for the preparation of heterodinuclear [mu]-aminocarbyne complexes, since the basic imine-type N atom of the ...
Access
Discipline
- Chemistry, inorganic & nuclear
- Genetics & heredity
- Environmental sciences
- Paleontology
- Archaeology
- Geosciences, multidisciplinary
- Geography, physical
- Geology
- Limnology
- Ecology
- Crystallography
- Biodiversity conservation
- Astronomy & astrophysics
- Water resources
- Chemistry, organic
- Meteorology & atmospheric sciences
- Geochemistry & geophysics
- Microbiology
- Physics, atomic, molecular & chemical
- History
- Mineralogy
- Cell biology
- Materials science, multidisciplinary
- Spectroscopy
- Multidisciplinary sciences
- Plant sciences
- Agronomy
- Chemistry, physical
- Chemistry, analytical
- Parasitology
- Physics, mathematical
- Engineering, environmental
- Health care sciences & services
- Biochemistry & molecular biology
- Computer science, information systems
- Forestry
- Mycology
- Mathematical & computational biology
- Materials science, characterization & testing
- Humanities, multidisciplinary
- Pathology
- Marine & freshwater biology
- Infectious diseases
- Oceanography
- Geography
- Oncology
- Ornithology
- Zoology
- Anatomy & morphology
- Behavioral sciences
- Computer science, artificial intelligence
- Cultural studies
- Entomology
- Instruments & instrumentation
- Materials science, biomaterials
- Medieval & renaissance studies
- Pharmacology & pharmacy
- Polymer science
- Remote sensing
- Toxicology
- Tropical medicine
- Nanoscience & nanotechnology
- Nuclear science & technology
- Engineering, chemical
- Computer science, theory & methods
- Communication
- Chemistry, applied
- Biophysics
- Biology, miscellaneous
- Agriculture, multidisciplinary
- Biology
- Physics, condensed matter
- Asian studies
- Physiology
- Architecture
- Acoustics
- Public, environmental & occupational health
- Religion
- Urban studies
- Reproductive biology
- Anthropology
- Statistics & probability
- Telecommunications
- Medical informatics
- Microscopy
- Materials science, composites
- Materials science, coatings & films
- Linguistics