Unusual Triplet-Triplet Annihilation in a 3D Copper Chloride Coordination Polymer
A new coordination polymer (CP) defined as [Cu2Cl2(EtS(CH2)4SEt)4]n (CP2) was prepared by reacting EtS(CH2)4SEt with CuCl in acetonitrile in a 1 : 2 stoichiometric ratio. The X-ray structure reveals formation of non-porous 3D material composed of parallel 2D-[Cu2Cl2S2]n layers of Cl-bridged ...
VizieR Online Data Catalog: Colors of the Outer Solar System Origins Survey
All the Colors of the Outer Solar System Origins Survey (Col-OSSOS) targets are drawn from the sample of over 800 trans-Neptunian objects (TNOs) and Centaurs (mr=21.8-25.2mag; 3.6<Hr<14.5mag) found by the OSSOS (Bannister+ 2016, J/AJ/152/70 ; 2018ApJS..236...18B 2018ApJS..236...18B), a survey with ...
VizieR Online Data Catalog: Outer Solar System Origins Survey (OSSOS). I
The Outer Solar System Origins Survey (OSSOS) observations are acquired in blocks: contiguous patches of sky formed by a layout of adjoining multiple 0.90deg2 MegaCam fields. The OSSOS discovery and tracking program uses the Canada-France-Hawaii Telescope (CFHT) MegaPrime/MegaCam. This paper covers ...
Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular Cu4I4S4 and Cu8I8S6 Clusters to Luminescent Copper(I) Coordination Polymers
The CuX salts (X = I, Br) react with SR2 to form molecular clusters of the types [(R2S)4(Cu4I4)] and [(R2S)6(Cu8I8)] or to give 1D polymers and 2D metal−organic frameworks. The cluster nuclearity and connectivity as well as the dimensionality of these compounds depend on the steric demand of SR2, ...
Bis{(4-methylthio)phenylthio}methane as assembling ligand for the construction of Cu(I) and Hg(II) coordination polymers. Crystal structures and topological (AIM) analysis of the bonding
The novel 1D coordination polymer (CP) [{Cu(μ2-Br)2Cu}(μ-L2)2] CP2 has been obtained by reaction of the tetrakisthioether p-MeSC6H4SCH2SC6H4SMe-p (L2) with CuBr in a 1:2 metal-to ligand ratio. In contrast to the previously described CP [{Cu(μ2-Br)2Cu}(μ-L1)2] CP1 obtained by reaction of the ...