4,4-Bis(4-methylphenylsulfanyl)-1,1-diphenyl-2-azabuta-1,3-diene (2008)
Available
Dataset
Licence : CC BY-NC-SA doi:10.25666/DATAOSU-2016-08-23-02 doi:10.1107/S1600536807066615
Data creators :
Abderrahim Khatyr [1] [2],
Hamid Boudiba [1] [2],
Marek M. Kubicki [3],
Michael Knorr [1] [2],
Rodolphe Kinghat [1] [2]
[1] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[2] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
[3] : Institut de Chimie Moléculaire de l'Université de Bourgogne (UMR 6302) (Université de Bourgogne)
Description :
In the title compound, C29H25NS2, both the Cl atoms of the azadiene precursor 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene are replaced by two vicinal S-p-tolyl substituents attached to the terminal C atom of a [pi]-conjugated 2-azabutadiene array. The azadiene chain is planar to within 0.01 Å. One of the phenyl rings seems to be slightly [pi]-conjugated with the azadiene core [dihedral angle 5.1 (2)°].
Discipline :
crystallography (chemistry)
Keywords :
General metadata
Data acquisition date :
2007
Data acquisition methods :
- Experimental data : Diffraction des rayons-X - Synthèse organique
Language :
English (eng)
Formats :
chemical/x-cif
Audience :
University: master, Research
Publications :
- 4,4-Bis(4-methylphenylsulfanyl)-1,1-diphenyl-2-azabuta-1,3-diene (http://journals.iucr.org/e/issues/2008/02/00/gw2031/)
Collection :
Publisher :
International Union of Crystallography
DOI and links
10.25666/DATAOSU-2016-08-23-02
https://dx.doi.org/doi:10.25666/DATAOSU-2016-08-23-02
https://search-data.ubfc.fr/FR-18008901306731-2016-08-23-02
Quotation
Abderrahim Khatyr, Hamid Boudiba, Marek M. Kubicki, Michael Knorr, Rodolphe Kinghat (2008): 4,4-Bis(4-methylphenylsulfanyl)-1,1-diphenyl-2-azabuta-1,3-diene. IUCr. doi:10.25666/DATAOSU-2016-08-23-02
Record created 23 Aug 2016 by Michael Knorr.
Local identifier: FR-18008901306731-2016-08-23-02.
