[μ-Bis(diphenylphosphanyl)methane]-tricarbonyl(μ-p-toluenesulfonylmethylisocyanato)(triphenylphosphane)iron-platinum(Fe-Pt) (2012)
Available
Dataset
Licence : CC BY-NC-SA doi:10.25666/DATAOSU-2016-07-22 doi:10.1107/S1600536812004023
Data creators :
Carsten Strohmann [1],
Isabelle Jourdain [2] [3],
Michael Knorr [2] [3],
Stephan Koller [1]
[1] : Technische Universität Dortmund
[2] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[3] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
Description :
The title compound, [FePt(C9H9NO2S)(C18H15P)(C25H22P2)(CO)3], represents a rare example of an isonitrile-bridged heterobimetallic complex (here Pt and Fe) and is an interesting precursor for the preparation of heterodinuclear [mu]-aminocarbyne complexes, since the basic imine-type N atom of the [mu]2-C=N-R ligand readily undergoes addition with various electrophiles to afford iminium-like salts. In the crystal, the almost symmetrically bridging [mu]2-C=N-R ligand (neglecting the different atomic radii of Fe and Pt) is strongly bent towards the Fe(CO)3 fragment, with a C=N-R angle of only 121.1 (4)°.
Disciplines :
General metadata
Data acquisition date :
from 2011 to 2012
Data acquisition methods :
- Experimental data : Diffraction des rayons X
Language :
English (eng)
Formats :
chemical/x-cif
Audience :
University: master, Research
Publications :
- [[mu]-Bis(diphenylphosphanyl)methane]tricarbonyl([mu]-p-toluenesulfonylmethyl isocyanato)(triphenylphosphane)ironplatinum(Fe-Pt) (http://journals.iucr.org/e/issues/2012/03/00/fi2121/index.html)
Collection :
Publisher :
International Union of Crystallography
Record created 22 Jul 2016 by Michael Knorr.
Local identifier: FR-18008901306731-2016-07-22.
