Crystal structure of di-[mu]-iodido-bis[bis(acetonitrile-[kappa]N)copper(I)] (2015)
Available
Dataset
Licence : CC BY-NC-SA doi:10.25666/DATAOSU-2016-07-19 ccdc:1427944 doi:10.1107/S2056989015018149
Data creators :
Eva Rebecca Barth [1],
Christopher Golz [1],
Michael Knorr [2] [3],
Carsten Strohmann [1]
[1] : Technische Universität Dortmund
[2] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[3] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
Description :
The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu...Cu distance = 2.7482 (11) Å], the CuI atoms of which are further coordinated by four molecules of acetonitrile. The CuI atom has an overall distorted tetrahedral coordination environment evidenced by L-Cu-L angles (L = N or I) ranging from 100.47 (10) to 117.06 (2)°. The coordination geometries of the acetonitrile ligands deviate slightly from linearity as shown by Cu-N-C angles of 167.0 (2) and 172.7 (2)°. In the crystal, there are no significant hydrogen-bonding interactions present, so the crystal packing seems to be formed predominantly by van der Waals forces.
Disciplines :
General metadata
Data acquisition date :
2013
Data acquisition methods :
Language :
English (eng)
Formats :
chemical/x-cif
Audience :
University: master, Research
Publications :
- Crystal structure of di-[mu]-iodido-bis[bis(acetonitrile-[kappa]N)copper(I)] (http://journals.iucr.org/e/issues/2015/11/00/wm5208/)
Collection :
Publisher :
International Union of Crystallography
Record created 19 Jul 2016 by Michael Knorr.
Last modification : 24 Sep 2021.
Local identifier: FR-18008901306731-2016-07-19.
