Crystal structure of di-[mu]-iodido-bis[(dimethyl sulfoxide-[kappa]O)(triphenylphosphane-[kappa]P)copper(I)] (2014)
Available
Dataset
Licence : CC BY-NC-SA doi:10.25666/DATAOSU-2016-07-19-03 ccdc:1034622 doi:10.1107/S1600536814025203
Data creators :
Rodolphe Kinghat [1] [2],
Michael Knorr [1] [2],
Marek M. Kubicki [3],
Yoann Rousselin [3]
[1] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[2] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
[3] : Institut de Chimie Moléculaire de l'Université de Bourgogne (UMR 6302) (Université de Bourgogne)
Description :
The centrosymmetric dinuclear title compound, [Cu2I2(C2H6OS)2(C18H15P)2], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated CuI atoms are bridged by two [mu]2-iodido ligands in an almost symmetrical rhomboid geometry. The loose Cu...Cu contact of 2.9874 (8) Å is longer than the sum of the van der Waals radii of two Cu atoms (2.8 Å), excluding a significant cupriophilic interaction in the actual dimer. C-H...O and C-H...I hydrogen bonding interactions as well as C-H...[pi](aryl) interactions stabilize the three-dimensional supramolecular network.
Disciplines :
General metadata
Data acquisition date :
2010
Data acquisition methods :
- Experimental data : Diffraction des rayons X
Language :
English (eng)
Formats :
chemical/x-cif
Audience :
University: master, Research
Publications :
- Crystal structure of di-μ-iodido-bis[(dimethyl sulfoxide-κO)(triphenylphosphane-κP)copper(I)] (http://journals.iucr.org/e/issues/2014/12/00/gk2619/)
Collection :
Publisher :
International Union of Crystallography
DOI and links
10.25666/DATAOSU-2016-07-19-03
https://dx.doi.org/doi:10.25666/DATAOSU-2016-07-19-03
https://search-data.ubfc.fr/FR-18008901306731-2016-07-19-03
Quotation
Rodolphe Kinghat, Michael Knorr, Marek M. Kubicki, Yoann Rousselin (2014): Crystal structure of di-[mu]-iodido-bis[(dimethyl sulfoxide-[kappa]O)(triphenylphosphane-[kappa]P)copper(I)]. IUCr. doi:10.25666/DATAOSU-2016-07-19-03
Record created 19 Jul 2016 by Michael Knorr.
Last modification : 24 Sep 2021.
Local identifier: FR-18008901306731-2016-07-19-03.
