Suretta nappe shear zones
The database "Suretta nappe shear zones" contains petrological, structural and microtextural data of millimetre-scale shear zones from the Roffna rhyolite (Suretta nappe, Eastern Alps, Switzerland). The data consist of structural orientations, optical and electronic images of the mineralogy of the ...
Crystal structure of dicarbonyl[μ2-methylenebis(diphenylphosphane)-κ2P:P′][μ2-2-(2,4,5-trimethylphenyl)-3-...
The title compound, [FePt(C12H12O)(C18H15P)(C25H22P2)(CO)2]·2C7H8·CH2Cl2 or [(OC)2Fe(μ-dppm)(μ-C(=O)C(2,4,5-C6H2Me3)=CH)Pt(PPh3)], represents an example of a diphosphane-bridged heterobimetallic dimetallacyclopentenone complex resulting from a bimetallic activation of 1-ethynyl-2,4,5-trimethylbe ...
Crystal structure of 2-[bis(benzylsulfanyl)methyl]-6-methoxyphenol
The title compound, C22H22O2S2, 1, represents an example of an ortho-vanillin-based functionalized dithioether, which could be useful as a potential chelating ligand or bridging ligand for coordination chemistry. This dithioacetal 1 crystallizes in the orthorhombic space group Pbca. The phenyl ...
Crystal structure of {μ2-1,2-bis[(4-methylphenylsulfanyl]-3-oxoprop-1-ene-1,3-diyl-1:2κ2C3:C1}dicarbonyl-1κ2C-[μ2-methylenebis(diphenylphosphane)-1:2κ2P:P′](triphenylphosphane-2κP)ironplatinum(Fe—Pt),...
The title compound, [FePt(C19H18OS2)(C18H15P)(C25H22P2)(CO)2], 1, [(OC)2Fe(μ-dppm)(μ-C(=O)C(CH2SC6H4Me-4)=CCH2SC6H4Me-4)Pt(PPh3)], represents the first example of a diphosphane-bridged heterobimetallic Fe—Pt dimetallacyclopentenone complex resulting from a bimetallic activation of ...
Crystal structures of 9-[bis(benzylsulfanyl)methyl]anthracene and of cyclo-dodecakis(μ2-phenylmethanethiolato-κ2S:S)hexapalladium(6 Pd—Pd)–anthracene-9,10-dione (1/1)
The first title compound, C29H24S2, L1, represents an example of an anthracene-based functionalized dithioether, which may be useful as a potential chelating or terminal ligand for coordination chemistry. This dithioacetal L1 crystallizes in the monoclinic space group P21/c. The phenyl rings of ...
Pollen analysis - Saint-Romain-de-Jalionas (F-38), marais de la Besseye
Holocene clayey marsh between glacial moraines and river beds of the Bionnay and Girondan, at the foot of the Crémieu limestone plateau. 24 palynological samples.
Pollen analysis - Mondragon (F-84), Les Ribaudes
Gallic drainage and irrigation network identified in the Holocene floodplain of the Rhone valley (south of Tricastin), 6 palynological samples at MD-RIB S1-583 and 59-7175.
Phytomanagement - Bernburg (DE)
In the frame of the NETFIB project, the project partners study the production of nettle in agro-forestry systems, within a poplar-phytomanaged plantation, aiming at lowering the impact of degradation of polluted sites while maximazing ecosystem services. The objective of the production of the ...
Synthesis of Tris(arylphosphite)-ligated Cobalt(0) Complexes [Co2(CO)6{P(OAr)3}2], and their Reactivity towards Phenylacetylene and Diphenylacetylene
The dinuclear complexes [Co2(CO)6{P(OAr)3}2] (1a, Ar = Ph; 1b, Ar = o-Tol) were prepared and reacted with PhC≡CH and PhC≡CPh to yield dimetallatetrahedranes [{(ArO)3P}(OC)2Co-Co(μ-RC≡CPh)(CO)2{P(OAr)3}] (3a, Ar = Ph, R = H; 3b, Ar = o-Tol, R = H; 3c, Ar = Ph, R = Ph; 3d, Ar = o-Tol, R = Ph). The ...
Crystal structure of the coordination polymer catena-poly[[[(acetonitrile-κN)copper(I)]-μ3-1,3-dithiolane -κ3S:S:S'] hexafluoridophosphate]
The polymeric title compound, [Cu2(C2H3N)2(C3H6S2)2](PF6)2, represents an example of a one-dimensional coordination polymer resulting from the reaction of [Cu(MeCN)4][PF6] with 1,3-dithiolane. The cationic one-dimensional ribbon consists of two copper(I) centers each ligated by one acetonitrile ...
Unusual Triplet-Triplet Annihilation in a 3D Copper Chloride Coordination Polymer
A new coordination polymer (CP) defined as [Cu2Cl2(EtS(CH2)4SEt)4]n (CP2) was prepared by reacting EtS(CH2)4SEt with CuCl in acetonitrile in a 1 : 2 stoichiometric ratio. The X-ray structure reveals formation of non-porous 3D material composed of parallel 2D-[Cu2Cl2S2]n layers of Cl-bridged ...
Three-Component Access to Functionalized Spiropyrrolidine Heterocyclic Scaffolds and Their Cholinesterase Inhibitory Activity
A novel one-pot [3+2]-cycloaddition reaction of (E)-3-arylidene-1-phenyl-succinimides, cyclic 1,2-diketones (isatin, 5-chloro-isatin and acenaphtenequinone), and diverse α-aminoacids such as 2-phenylglycine or sarcosine is reported. The reaction provides succinimide-substituted dispiropyrrolidine ...
Pollen analysis - Rochefort (Suisse, Neuchâtel), Cotencher Cave
10 palynological samples taken from lower levels (older than 72,000 years). Partly sterile or very corrosive. Interesting presence of hornbeam (Carpinus) mixed with steppics in a sample.
Pollen analysis - Beffia (F-39), Tumulus 2001, En Magne ou sur Magne
5 palynological samples at the heart of the main burial ground. Almost sterile.
Pollen analysis - Sciez (F-74), Chemin de la Renouillère
Archaeologiocal site. Plain in edge of a lake. 4 palynological samples.
Pollen analysis - Les Eyzies-de-Tayac-Sireuil (F-26), 28 avenue de la Forge, calcareous tuff
A single palynological sample from a layer of calcareous tuff. Sterile.
Pollen analysis - Siracusa (Sicile, Italie), Aqueduc du Galermi
A single palynological sample from carbonates in a Roman aqueduct. Poor but exploitable.
Pollen analysis - Saint Benoît (F-86), Pièces de la Chaume, carbonates from a Gallo-Roman aqueduct
Two palynological samples taken from a carbonate inking in the Gallo-Roman aqueduct of Poitiers. Poor.
Redetermination of the crystal structure of tetrammineplatinum(II) dichloride – A microporous hydrogen-bonded 3D network exhibiting a temperature-dependent order-disorder phase transition
The title compound [Pt(NH3)4]Cl2 (1), prepared by reaction of (NH4)2[PtCl4] with an excess of NH3 in aqueous solution, was crystallized from water and its structure redetermined by single-crystal X-ray diffraction at four different temperatures in the range from 273 K down to 100 K. 1 is composed of ...
Heterodinuclear Diphosphane-Bridged Iron–Platinum Diyne Complexes as Metalloligands for the Assembly of Polymetallic Systems (Fe, Pt, Co)
Treatment of [(OC)3Fe(μ-C=O)(µ-dppm)Pt(PPh3)] (1a) (dppm=Ph2PCH2PPh2) with 1,7-octadiyne affords the isomeric dimetallacyclopentenones [(OC)2Fe(µ-dppm)(µ-C(=O)C{(CH2)4C≡CH}=CH)Pt(PPh3)] (2a) and [(OC)2Fe(µ-dppm)(µ-C(=O)C(H)=C{(CH2)4C≡CH})Pt(PPh3)] (2a′). In a similar manner, the reaction with ...
Human recreational disturbance effects on chicks stress
Stress hormones, telomere lenght, and reproductive success for breeding bird in the Chaux forest.
3-spiroindolizines containing an isoindole ring through intra-molecular arylation of spiro-N-acyliminium species
Based on N-acyliminium species, efficient approaches to spirocyclic systems connected by two different carbon centers to the isoindole ring have been developed. The imide reduction and the tandem oxidative cleavage of olefin/formyl-amide equilibration were at first selected as the key steps for ...
Pure liquid phase recovery in karstic medium
This project is about the study in 2D-cells of fractured media, contaminated by pure phase hydrocarbons. Cosidered systems are made of 3 non-miscible fluids (air, water and hydrocarbons), considering light and dense hydrocarbons. First, the fluids behavior and the distribution of contaminants were ...
Continental weathering as a driver of Late Cretaceous cooling: new insights from clay mineralogy of Campanian sediments from the southern Tethyan margin to the Boreal realm
New clay mineralogical analyses have been performed on Campanian sediments from the Tethyan and Boreal realms along a palaeolatitudinal transect from 45° to 20°N (Danish Basin, North Sea, Paris Basin, Mons Basin, Aquitaine Basin, Umbria-Marche Basin and Tunisian Atlas). Significant terrigenous ...
DNA Library - CNR Echinococcoses
DNA Library is a database associated to a web interface, created to improve the storage and the life of a biological sample collection, closely related to the research activities of the National Reference Center for Echinococcosis (CNR Echinococcoses, University Hospital of Besançon, France). A ...
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