4,12-Bis(2,2-dibromovinyl)[2.2]paracyclophane (2009)
Available
Dataset
Licence : CC BY-NC-SA doi:10.25666/DATAOSU-2016-08-23-03 doi:10.1107/S1600536809002475
Data creators :
Carsten Strohmann [1],
Christian Däschlein [1],
Laurent Guyard [2] [3],
Michael Knorr [2] [3],
Sébastien Clément [2] [3]
[1] : Technische Universität Dortmund
[2] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[3] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
Description :
In the title compound, C20H16Br4, both vinylic substituents were introduced by a Corey-Fuchs reaction using 4,12-diformyl[2.2]paracyclophane as starting material. The title compound may be used as a valuable precursor for the synthesis of diethynyl[2.2]paracyclophane. The title molecule is centrosymmetric with a crystallographic center of inversion between the centers of the two phenyl rings. A strong tilting is observed with an interplanar angle between the best aromatic plane and the vinyl plane of 49.4 (5)°. No significant intermolecular interactions are found in the crystal.
Discipline :
crystallography (chemistry)
General metadata
Data acquisition date :
from 2008 to 2009
Data acquisition methods :
- Experimental data : Diffraction des rayons X - Synthèse organique
Language :
English (eng)
Formats :
chemical/x-cif
Audience :
University: master, Research
Publications :
- 4,12-Bis(2,2-dibromovinyl)[2.2]paracyclophane (http://journals.iucr.org/e/issues/2009/03/00/im2094/)
Collection :
Publisher :
International Union of Crystallography
DOI and links
10.25666/DATAOSU-2016-08-23-03
https://dx.doi.org/doi:10.25666/DATAOSU-2016-08-23-03
https://search-data.ubfc.fr/FR-18008901306731-2016-08-23-03
Quotation
Carsten Strohmann, Christian Däschlein, Laurent Guyard, Michael Knorr, Sébastien Clément (2009): 4,12-Bis(2,2-dibromovinyl)[2.2]paracyclophane. IUCr. doi:10.25666/DATAOSU-2016-08-23-03
Record created 23 Aug 2016 by Michael Knorr.
Local identifier: FR-18008901306731-2016-08-23-03.
