Crystal structure of di-[mu]-iodido-bis­[bis(aceto­nitrile-[kappa]N)copper(I)] (2015)

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Data creators : Eva Rebecca Barth [1], Christopher Golz [1], Michael Knorr [2] [3], Carsten Strohmann [1]
[1] : Technische Universität Dortmund
[2] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[3] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
Description :
The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu...Cu distance = 2.7482 (11) Å], the CuI atoms of which are further coordinated by four mol­ecules of aceto­nitrile. The CuI atom has an overall distorted tetra­hedral coordination environment evidenced by L-Cu-L angles (L = N or I) ranging from 100.47 (10) to 117.06 (2)°. The coordination geometries of the aceto­nitrile ligands deviate slightly from linearity as shown by Cu-N-C angles of 167.0 (2) and 172.7 (2)°. In the crystal, there are no significant hydrogen-bonding inter­actions present, so the crystal packing seems to be formed predominantly by van der Waals forces.
Disciplines :

General metadata

Data acquisition date : 2013
Data acquisition methods :
Language : English (eng)
Formats : chemical/x-cif
Audience : University: master, Research
Publications :
Record created 19 Jul 2016 by Michael Knorr.
Last modification : 24 Sep 2021.
Local identifier: FR-18008901306731-2016-07-19.

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