Crystal structure of tricarbonyl([mu]-diphenylphosphido-[kappa]2P:P)(methyldiphenylsilyl-[kappa]Si)bis(triphenylphosphane-[kappa]P)iron(II)platinum(0)(Fe-Pt) (2015)
Available
Dataset
Licence : CC BY-NC-SA doi:10.25666/DATAOSU-2016-07-19-02 doi:10.1107/S2056989015001565
Data creators :
Ahmed Said Mohamed [1] [2],
Isabelle Jourdain [1] [2],
Marek M. Kubicki [3],
Michael Knorr [1] [2],
Yoann Rousselin [3]
[1] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[2] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
[3] : Institut de Chimie Moléculaire de l'Université de Bourgogne (UMR 6302) (Université de Bourgogne)
Description :
The title compound, [FePt(C12H10P)(C13H13Si)(C18H15P)2(CO)3]·0.5CH2Cl2, represents an example of a phosphido-bridged heterobimetallic silyl complex; these are interesting precursors for the coordination and activation of small unsaturated organic molecules. The [mu]2-PPh2 ligand spans the iron and platinum atoms, which are connected via a metal-metal bond of 2.7738 (4) Å. In contrast to most other complexes of the [(OC)3Fe(SiR3)([mu]-PR2)PtL2] family, where the iron-bound SiR3 group is trans-arranged with respect to the [mu]2-PPh2 ligand, the SiPh2Me ligand is roughly collinear with the Fe-Pt vector [Si-Fe-Pt = 169.07 (3)°].
Disciplines :
General metadata
Data acquisition date :
2014
Data acquisition methods :
- Experimental data : Diffraction des rayons X
Language :
English (eng)
Formats :
chemical/x-cif
Audience :
University: master, Research
Publications :
- Crystal structure of tricarbonyl(μ-diphenylphosphido-κ2P:P)(methyldiphenylsilyl-κSi)bis(triphenylphosphane-κP)iron(II)platinum(0)(Fe—Pt) (http://journals.iucr.org/e/issues/2015/02/00/gk2624/)
Collection :
Publisher :
International Union of Crystallography
DOI and links
10.25666/DATAOSU-2016-07-19-02
https://dx.doi.org/doi:10.25666/DATAOSU-2016-07-19-02
https://search-data.ubfc.fr/FR-18008901306731-2016-07-19-02
Quotation
Ahmed Said Mohamed, Isabelle Jourdain, Marek M. Kubicki, Michael Knorr, Yoann Rousselin (2015): Crystal structure of tricarbonyl([mu]-diphenylphosphido-[kappa]2P:P)(methyldiphenylsilyl-[kappa]Si)bis(triphenylphosphane-[kappa]P)iron(II)platinum(0)(Fe-Pt). IUCr. doi:10.25666/DATAOSU-2016-07-19-02
Record created 19 Jul 2016 by Michael Knorr.
Last modification : 23 Aug 2016.
Local identifier: FR-18008901306731-2016-07-19-02.
