1-(4-Formyl-2,6-dimethoxyphenoxy)-4-chlorobut-2-yne
A reaction of biomass-derived aldehyde synringaldehyde and half an equivalent of 1,4-dichlorobut-2-yne was attempted in order to obtain a bis-aldehyde with an alkyne spacer. The reaction was carried out in a basic media to effect bis O-alkylation, as described in literature for the preparation of ...
4′-(5-Methylfuran-2-yl)-2,2′:6′,2″-terpyridine: A New Ligand Obtained from a Biomass-Derived Aldehyde with Potential Application in Metal-Catalyzed Reactions
The new ligand 4′-(5-methylfuran-2-yl)-2,2′:6′,2″-terpyridine (1) was prepared in one step from 2-acetylpyridine and 5-methylfurfural. The latter is an aldehyde that can be readily obtained from biomass. The new terpyridine molecule was characterized by 1H and 13C-NMR spectroscopy as well as by ...
Diversity-oriented Synthesis of Spiropyrrolo[1, 2-a]isoquinoline Derivatives via Diastereoselective and Regiodivergent Three-component 1,3-Dipolar Cycloaddition Reactions: In vitro and in vivo Evaluation of the Antidiabetic Activity of Rhodanine Analogues
An efficient diastereoselective route is developed to get access to novel spiropyrrolo[1,2-a]isoquinoline-oxindole skeletons by a one-potthree-component [3 + 2] cycloaddition reaction of (Z)-5-arylidene-1,3-thiazolidine-2,4-diones, isatin derivatives, and 1,2,3,4-tetrahydroisoquinoline (THIQ). ...
Control of Structures and Emission Properties of (CuI)n 2-Methyldithiane Coordination Polymers
A structurally unique and strongly luminescent nonporous 3D coordination polymer (CP) [Cu8I8(methyldithiane)4]n, CP3, has been prepared in a quasi-anticipated manner from 2-methyl-1,3-dithiane, L1, and CuI. This CP incorporates an unprecedented Cu8I8 cluster built upon two side-fused open cubanes. ...
A Fused Poly(truncated rhombic dodecahedron)-Containing 3D Coordination Polymer: A Multifunctional Material with Exceptional Properties
The design of new and inexpensive metal-containing functional materials is of great interest. Herein is reported a unique thermochromic near-IR emitting coordination polymer, 3D-[Cu8I8(L1)2]n, CP2, which is formed when ArS(CH2)4SAr (L1, Ar = 4-C6H4OMe) reacts with 2 equiv of CuI in EtCN. In MeCN, ...
Crystal structure of di-[mu]-iodido-bis[bis(acetonitrile-[kappa]N)copper(I)]
The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu...Cu distance = 2.7482 (11) Å], the CuI atoms of which are further coordinated by four molecules of acetonitrile. The CuI atom has an overall distorted tetrahedral coordination environment evidenced by L-Cu-L angles (L ...
Crystal structure of di-[mu]-iodido-bis[(dimethyl sulfoxide-[kappa]O)(triphenylphosphane-[kappa]P)copper(I)]
The centrosymmetric dinuclear title compound, [Cu2I2(C2H6OS)2(C18H15P)2], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated CuI atoms are bridged by two [mu]2-iodido ligands in an almost symmetrical ...
Crystal structure of the two-dimensional coordination polymer poly[di-μ-bromido-bis(μ-tetrahydrothiophene)dicopper(I)]
The polymeric title compound, [Cu2Br2(C4H8S)2]n, CP1, represents an example of a two-dimensional coordination polymer resulting from reaction of CuBr with tetrahydrothiophene (THT) in MeCN solution. The two-dimensional layers consist of two different types of rhomboid-shaped dinuclear ...
4,4″-Dichloro-4′-(2-thienyl)-2,2′:6′,2″-terpyridine
A new thiophene-substituted terpyridine derivative has been prepared and characterized. This ligand features a thiophene heterocycle (as an electrochemically polymerizable unit) as well as two chlorine atoms for further functionalization.
4′-(N-(Propan-1,2-dienyl)pyrrol-2-yl)-2,2′:6′,2″-terpyridine
A new pyrrole-substituted terpyridine derivative that possesses an allene moiety was obtained as an “unexpected” sole product during an attempt to alkylate the N-atom of pyrrole with propargyl bromide in order to obtain an alkyne-functionalized terpyridine.
4′-(5-n-Propylthiophen-2-yl)-2,2′:6′,2″-terpyridine
A new thiophene-substituted terpyridine derivative has been prepared through the reaction between 5-n-propylthiophene-2-carboxaldehyde and 2-acetylpyridine. This terpyridine derivative bears an alkyl chain linked via a thiophene heterocycle.
Pollen analysis - Le Locle (NE, CH), Col des Roches (Projet H20)
The archaeological surveys carried out on the Le Locle bypass road have made it possible to make several test borring in the upper part of the fill of the area located south of the city, between the city and the Col des Roches, in the Marais des Calame and Marais de la Molière. Two sections were ...
Pollen analysis - Fontenu (F-39), Domaine CID I et CID II
Two boreholes (CID I of 5.77 m and CID II of 7.63 m) were drilled off the Domaine de Chalain (east bank), 65-70 m from the shore. 57 pollen samples were taken from CID I and 21 from CID II + 5 radiocarbon dates.
Pollen analysis - La Châteleine (F-39), Au vieux château
Only one sample in a natural depression in the heart of the castle excavation.
BIOTROPH - Molecular Ecology
A data set for the project ‘BIOTROPH’. The aim of this study was to estimate functional role of the taxonomic diversity of available resources in the field on trophic exposure of small mammals (wood mice ‘Apodemus sylvaticus’) to trace metals (TM; principally cadmium, lead and zinc). The data was ...
CECURE-Contamination of the Environment and Circulation in Urban and Rural areas of Echinococcus multilocularis
A copro-sample collection was created for the CECURE project. The aim of this study was to assess the relative role of carnivore hosts (mainly fox, dog, cat) in the speading and circulation of the parasite Echinococcus multilocularis in the urban and rural environnement in order to assess the ...
Genotypic and phenotypic evolution of a Pseudomonas aeruginosa ST395 strain during 11-year in hospital spread.
P. aeruginosa is an opportunistic pathogen responsible of hospital-acquired infections in immunocompromised patients. Although in-host evolution of P. aeruginosa is well documented, little is known about this pathogen evolution during its spread on a hospital scale. The high-risk multidrug resistant ...
Data on genes expression in Pseudomonas aeruginosa
Pseudomonas aeruginosa is a Gram-negative Human opportunistic pathogen, responsible for nosocomial infections with high mortality for immunocompromised patients. The pathogenesis is based on the production of many structural or secreted virulence factors. P. aeruginosa is also able to produce ...
Suretta nappe shear zones
The database "Suretta nappe shear zones" contains petrological, structural and microtextural data of millimetre-scale shear zones from the Roffna rhyolite (Suretta nappe, Eastern Alps, Switzerland). The data consist of structural orientations, optical and electronic images of the mineralogy of the ...
Crystal structure of dicarbonyl[μ2-methylenebis(diphenylphosphane)-κ2P:P′][μ2-2-(2,4,5-trimethylphenyl)-3-...
The title compound, [FePt(C12H12O)(C18H15P)(C25H22P2)(CO)2]·2C7H8·CH2Cl2 or [(OC)2Fe(μ-dppm)(μ-C(=O)C(2,4,5-C6H2Me3)=CH)Pt(PPh3)], represents an example of a diphosphane-bridged heterobimetallic dimetallacyclopentenone complex resulting from a bimetallic activation of 1-ethynyl-2,4,5-trimethylbe ...
Crystal structure of 2-[bis(benzylsulfanyl)methyl]-6-methoxyphenol
The title compound, C22H22O2S2, 1, represents an example of an ortho-vanillin-based functionalized dithioether, which could be useful as a potential chelating ligand or bridging ligand for coordination chemistry. This dithioacetal 1 crystallizes in the orthorhombic space group Pbca. The phenyl ...
Crystal structure of {μ2-1,2-bis[(4-methylphenylsulfanyl]-3-oxoprop-1-ene-1,3-diyl-1:2κ2C3:C1}dicarbonyl-1κ2C-[μ2-methylenebis(diphenylphosphane)-1:2κ2P:P′](triphenylphosphane-2κP)ironplatinum(Fe—Pt),...
The title compound, [FePt(C19H18OS2)(C18H15P)(C25H22P2)(CO)2], 1, [(OC)2Fe(μ-dppm)(μ-C(=O)C(CH2SC6H4Me-4)=CCH2SC6H4Me-4)Pt(PPh3)], represents the first example of a diphosphane-bridged heterobimetallic Fe—Pt dimetallacyclopentenone complex resulting from a bimetallic activation of ...
Crystal structures of 9-[bis(benzylsulfanyl)methyl]anthracene and of cyclo-dodecakis(μ2-phenylmethanethiolato-κ2S:S)hexapalladium(6 Pd—Pd)–anthracene-9,10-dione (1/1)
The first title compound, C29H24S2, L1, represents an example of an anthracene-based functionalized dithioether, which may be useful as a potential chelating or terminal ligand for coordination chemistry. This dithioacetal L1 crystallizes in the monoclinic space group P21/c. The phenyl rings of ...
Pollen analysis - Saint-Romain-de-Jalionas (F-38), marais de la Besseye
Holocene clayey marsh between glacial moraines and river beds of the Bionnay and Girondan, at the foot of the Crémieu limestone plateau. 24 palynological samples.
Pollen analysis - Mondragon (F-84), Les Ribaudes
Gallic drainage and irrigation network identified in the Holocene floodplain of the Rhone valley (south of Tricastin), 6 palynological samples at MD-RIB S1-583 and 59-7175.
Discipline
- crystallography
- environmental sciences
- chemistry, organic
- microbiology
- archaeology
- geology
- geosciences, multidisciplinary
- materials science, multidisciplinary
- chemistry, inorganic & nuclear
- cell biology
- engineering, environmental
- chemistry, physical
- ecology
- forestry
- mycology
- water resources
- mineralogy
- computer science, software engineering
- biodiversity conservation
- parasitology
- mathematical & computational biology
- history
- geography, physical
- materials science, characterization & testing
- geochemistry & geophysics
- biochemistry & molecular biology
- electrochemistry
- energy & fuels
- engineering, electrical & electronic
- geography
- polymer science
- imaging science & photographic technology
- infectious diseases
- language & linguistics
- marine & freshwater biology
- materials science, biomaterials
- agronomy
- materials science, coatings & films
- entomology
- engineering, mechanical
- mechanics
- medical informatics
- medieval & renaissance studies
- engineering, chemical
- dermatology
- music
- computer science, information systems
- neurosciences
- ornithology
- paleontology
- chemistry, applied
- pathology
- physics, atomic, molecular & chemical
- behavioral sciences
- psychology, experimental
- remote sensing
- robotics
- surgery
- toxicology
- transportation science & technology
- urban studies
- health care sciences & services
Structure
Project
- Thèse de doctorat en géologie - Jonas Vanardois
- NETFIB
- Thèse de doctorat en biologie des populations et écologie - Chloé Viotti
- Elaboration des composés héterocycliques antidiabétiques et antimicrobiens
- Bourse post-doctorale - Abhinav Raghuvanshi
- Elaboration des matériaux luminescents
- Thèse de doctorat en sciences de la vie et de l’environnement - Cyril Zappelini
- CREAM - Cracking the emotional code of music
- ECOPOLIS
- Effet du réchauffement climatique sur le système immunitaire des ravageurs phytophages et son impact sur les interactions trophiques
- Etude de dépôts sur surfaces organiques et inorganiques : application au colmatage des membranes et aux films minces conducteurs
- Évolution génotypique et phénotypique d'une souche épidémique de Pseudomonas aeruginosa au cours des 12 ans de sa diffusion hospitalière
- EWET - EmsB Website for Echinococcus Typing
- FIBROKARST - Caractérisation des processus de recharge dans un système karstique : Scan dynamique 3D et mesures par fibre optique
- Fondation pour l'audition
- FREIDI-Hg
- French RENATECH network (program P-14-00805)
- Impact de la modification de membrane commerciales par polymérisation par plasma froid sur les performances de filtration d’ions métalliques et le colmatage
- KARSTNAPL : Comportement et élimination de phases liquides non aqueuses dans des modèles d’aquifères fracturés et fissurés
- Nouveaux traceurs isotopiques du volcanisme d’échelle stratosphérique
- PHM PAC
- PHYTOCHEM
- PHYTOFIBER
- Polarimetric Vision Applied to Robotics Navigation - ViPeR
- PROLIPHYT
- Récupération de phases liquides organiques en milieu karstique
- REFLETS - Rétroaction Émotionnelle Faciale et Linguistique, et États de stress post-Traumatiques
- Salsigne
- SENSAAS
- SEPIA - Processus sensoriels et émotionnels dans les troubles du spectre de l'autisme
- SKUB
- Thèse de doctorat en agronomie - Ababdoulaye Mahamat Malabad
- Thèse de doctorat en biochimie et biologie moléculaire - Mélanie Grosjean
- Thèse de doctorat en biologie des populations et écologie - Jordan Collot
- Thèse de doctorat en chimie - Florian Charrier
- Thèse de doctorat en chimie - Lena Knauer
- Thèse de doctorat en chimie - Lukas Brieger
- Thèse de doctorat en géologie - Jean-Charles Poilvet
- Thèse de doctorat en instrumentation et informatique de l'image - Marc Blanchon
- Thèse de doctorat en instrumentation et informatique de l'image - Rita Meziati Sabour
- Thèse de doctorat en sciences de la vie et de la santé - Marie Petitjean
- Thèse de doctorat en sciences de la vie et de l’environnement - Alexis Durand
- Thèse de doctorat en sciences de la vie et de l’environnement - José Zapata Carbonell
- Thèse de doctorat en sciences de la vie et de l’environnement - Loic Yung
- Thèse de doctorat en sciences de la vie et de l’environnement - Mohamad Assad
- Thèse de doctorat en sciences pour l'ingénieur - Aflah Elouneg
- Thèse de doctorat en sismologie environnementale - Anthony Abi Nader
- Thèse de doctorat en structure et évolution de la terre - Bertil Nlend
- BIOFILTREE
- TRANSKARST
- BIOTROPH - Influence de la biodiversité sur les transferts de contaminants dans les réseaux trophiques
- CECURE - Contamination of the Environment and Circulation in Urban and Rural areas of Echinococcus multilocularis
- Chrysalide
- CO-CONPAC
- Colorado Plateau xenoliths projects
- Conséquences du dérangement liés aux activités de loisirs sur la réponse au stress chez les mésanges
Collection
- Single-crystal X-ray structures
- Données de thèse
- PollenChrono
- Organic synthesis
- Phytomanagement-Chrono
- Dynamique des orogènes anciennes
- Données de thèse de Jonas Vanardois
- Bioorganic synthesis
- Inorganic synthesis
- CNR Echinococcoses
- Pile à combustible
- Elaboration des matériaux luminescents
- Hydrogène
- Faults and shear zones
- Neuro group @ FEMTO-ST
- Génomique bactérienne
- Organometallic complexes with metal-metal bonds
