Triphenylphosphane
Translations : triphenylphosphane, triphénylphosphane
Frame of reference : The IUPAC International Chemical Identifier identified by 1/C18H15P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)1
Crystal structure of di-[mu]-iodido-bis[(dimethyl sulfoxide-[kappa]O)(triphenylphosphane-[kappa]P)copper(I)]
Disciplines :
chemistry, inorganic & nuclear
crystallography
Collected date : 2010
The centrosymmetric dinuclear title compound, [Cu2I2(C2H6OS)2(C18H15P)2], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated CuI atoms are bridged by two [mu]2-iodido ligands in an almost symmetrical ...
