Chemistry
Translations : chemistry ; chimie
- chemistry, analytical
- chemistry, applied
- chemistry, inorganic & nuclear
- chemistry, organic
- chemistry, physical
- crystallography
- electrochemistry
- materials science, characterization & testing
- materials science, coatings & films
- materials science, composites
- materials science, multidisciplinary
- nanoscience & nanotechnology
- polymer science
Model energetic macroscopic representation (EMR) of the Fuel Cell and leads to a so-called maximal control structure (MCS)
This modeling presents the control part of a proton exchange membrane fuel cell (PEMFC). The objective of the model is to represent the voltage control chain of the PEMFC. This model is based on an energetic macroscopic representation (EMR) of the fuel cell and then leads to a so-called maximum ...
4’-(N-(2-cyanoethyl)pyrrol-2-yl)-2,2’:6’,2’’-terpyridine
Data for the synthesis and caracterization of 4’-(N-(2-cyanoethyl)pyrrol-2-yl)-2,2’:6’,2’’-terpyridine.
4′-(N-(Propargyl)pyrrol-2-yl)-2,2′:6′,2′′-terpyridine
A new terpyridine molecule, bearing a N-propargylated pyrrole, was prepared and characterized. Its synthesis was based on a Krohnke-type reaction between 2-acetylpyridine and N-propargylpyrrole-2-carboxaldehyde in a basic medium. An allene-containing terpyridine was also obtained as a by-product.
Physicochemical characteristics of water and sediment - floodplains of the Ain, Doubs and Loue Rivers - 2015-2016
19 sites (16 wetlands and 3 rivers) with different physicochemical characteristics and distributed along three rivers (Ain, Doubs, and Loue) were sampled. The physicochemical characteristics of the wetlands were measured in situ or after laboratory analysis.
Physicochemical characteristics of water and sediment - Ain River floodplain - 2019-2020
34 sites (16 wetland sites, 15 river sites, and 3 groundwaters) distributed along the Ain River with different physicochemical characteristics were sampled. The physicochemical characteristics of the wetlands were measured in situ or after laboratory analysis.
1-{4-[(Hexyloxy)methyl]pyridin-2-yl}ethanone
A new member of the 2-acetylpyridine family has been prepared and characterized by NMR and IR spectroscopies.
IEEE PHM Data Challenge 2014
This data set is divided in two parts in the framework of the IEEE PHM Data Challenge 2014. The first part is a 1kW proton exchange membrane fuel cell on which long-term tests (1,000 hours) have been carried out under quasi-stationary conditions. The second part also deals with a fresh 1kW proton ...
Pronostics & Health Management of fuel cell systems project
The PHM-PAC project is mainly aimed at developing intelligent methods for the detection, diagnosis and prognosis of fuel cell failures. This project should allow the optimization of the performance of fuel cell systems as well as a better understanding of the electrochemical phenomena affecting the ...
Electric vehicle energy model
The project is a simple electric vehicle energy model. It uses the fundamental principle of dynamics to determine the power profile seen by a battery cell for a given mission. The input data are GPX files of the actual path considered. They can also be replaced by a speed and slope profile. In the ...
Modeling the aging of battery and fuel cell components in real use
These models are associated with the project AsDeCoEUR (Analyses De Composants Energétiques en Usage Réel). The project is based on a thesis work aiming at understanding the dynamic behavior, to study the aging and to estimate the health status of the battery and fuel cell energy components in real ...
In vivo skin anisotropy dataset for a young man (28 years old) by annular suction
The aim of our study is to characterize the anisotropic and viscoelastic behavior of the skin. Thus, a campaign of in vivo ring suction tests was conducted using the CutiScan®CS100 device from Courage and Khazaka electronics. 30 tests were performed on the anterior forearm of a 28-year-old Caucasian ...
New spiropyrrolothiazole derivatives bearing an oxazolone moiety as potential antidiabetic agent: Design, synthesis, crystal structure, Hirshfeld surface analysis, ADME and molecular docking studies
In a sustained search for novel and effective antihyperglycemics, a new series of fifteen isomeric oxazolone-fused dispiropyrrolothiazoles resulting from one-pot three component reaction between L-4-thiazolidine carboxylic acid, arylidene-oxazolones and isatin (or acenaphthenequinone) has been ...
Antimicrobial Activity and DFT Studies of a Novel Set of Spiropyrrolidines Tethered with Thiochroman-4-one/Chroman-4-one Scaffolds
A novel series of 14 spiropyrrolidines bearing thiochroman-4-one/chroman-4-one, and oxindole/acenaphthylene-1,2-dione moieties were synthesized and characterized by spectroscopic techniques, as well as by three X-ray diffraction studies, corroborating the stereochemistry. Quantum chemical ...
Synthesis, antidiabetic activity and molecular docking study of rhodanine-substitued spirooxindole pyrrolidine derivatives as novel α-amylase inhibitors
In a sustained search for novel α-amylase inhibitors for the treatment of type 2 diabetes mellitus (T2DM), we report herein the synthesis of a series of nineteen novel rhodanine-fused spiro[pyrrolidine-2,3′-oxindoles]. They were obtained by one-pot three component [3 + 2] cycloaddition of stabilized ...
Pressure-Temperature quantification of continental crustal hydration - Colorado Plateau
Data acquired in collaboration with the University of Boulder in Colorado (U.S.A.) for the understanding of the Colorado Plateau elevation. These data sets include mineralogical, petrological, chemical, pressure-temperature modelisation and density evolution.
Impact of a treatment by plasma polymerization on the filtration performances of commercial membranes for the decontamination of solution containing metal ions.
In this project, a commercial membrane exhibiting low performances of heavy metal removal has been modified by plasma grafting of poly(allylamine). This treatment allows modifying the structural and physicochemical properties of the membrane surface and thus increasing separation performances, while ...
Nitrogen Hydrate Cage Occupancy and Bulk Modulus Inferred from Density Functional Theory-Derived Cell Parameters
Gas clathrate hydrate solid materials, ubiquitous in nature as found either on the ocean floor, permafrost on the Earth, or in extraterrestrial planets and comets, are also technologically relevant, for example, in energy storage or carbon dioxide sequestration. Nitrogen hydrate, in particular, is ...
1-(4-Formyl-2,6-dimethoxyphenoxy)-4-chlorobut-2-yne
A reaction of biomass-derived aldehyde synringaldehyde and half an equivalent of 1,4-dichlorobut-2-yne was attempted in order to obtain a bis-aldehyde with an alkyne spacer. The reaction was carried out in a basic media to effect bis O-alkylation, as described in literature for the preparation of ...
4′-(5-Methylfuran-2-yl)-2,2′:6′,2″-terpyridine: A New Ligand Obtained from a Biomass-Derived Aldehyde with Potential Application in Metal-Catalyzed Reactions
The new ligand 4′-(5-methylfuran-2-yl)-2,2′:6′,2″-terpyridine (1) was prepared in one step from 2-acetylpyridine and 5-methylfurfural. The latter is an aldehyde that can be readily obtained from biomass. The new terpyridine molecule was characterized by 1H and 13C-NMR spectroscopy as well as by ...
Diversity-oriented Synthesis of Spiropyrrolo[1, 2-a]isoquinoline Derivatives via Diastereoselective and Regiodivergent Three-component 1,3-Dipolar Cycloaddition Reactions: In vitro and in vivo Evaluation of the Antidiabetic Activity of Rhodanine Analogues
An efficient diastereoselective route is developed to get access to novel spiropyrrolo[1,2-a]isoquinoline-oxindole skeletons by a one-potthree-component [3 + 2] cycloaddition reaction of (Z)-5-arylidene-1,3-thiazolidine-2,4-diones, isatin derivatives, and 1,2,3,4-tetrahydroisoquinoline (THIQ). ...
Control of Structures and Emission Properties of (CuI)n 2-Methyldithiane Coordination Polymers
A structurally unique and strongly luminescent nonporous 3D coordination polymer (CP) [Cu8I8(methyldithiane)4]n, CP3, has been prepared in a quasi-anticipated manner from 2-methyl-1,3-dithiane, L1, and CuI. This CP incorporates an unprecedented Cu8I8 cluster built upon two side-fused open cubanes. ...
A Fused Poly(truncated rhombic dodecahedron)-Containing 3D Coordination Polymer: A Multifunctional Material with Exceptional Properties
The design of new and inexpensive metal-containing functional materials is of great interest. Herein is reported a unique thermochromic near-IR emitting coordination polymer, 3D-[Cu8I8(L1)2]n, CP2, which is formed when ArS(CH2)4SAr (L1, Ar = 4-C6H4OMe) reacts with 2 equiv of CuI in EtCN. In MeCN, ...
Crystal structure of di-[mu]-iodido-bis[bis(acetonitrile-[kappa]N)copper(I)]
The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu...Cu distance = 2.7482 (11) Å], the CuI atoms of which are further coordinated by four molecules of acetonitrile. The CuI atom has an overall distorted tetrahedral coordination environment evidenced by L-Cu-L angles (L ...
Crystal structure of di-[mu]-iodido-bis[(dimethyl sulfoxide-[kappa]O)(triphenylphosphane-[kappa]P)copper(I)]
The centrosymmetric dinuclear title compound, [Cu2I2(C2H6OS)2(C18H15P)2], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated CuI atoms are bridged by two [mu]2-iodido ligands in an almost symmetrical ...
Crystal structure of the two-dimensional coordination polymer poly[di-μ-bromido-bis(μ-tetrahydrothiophene)dicopper(I)]
The polymeric title compound, [Cu2Br2(C4H8S)2]n, CP1, represents an example of a two-dimensional coordination polymer resulting from reaction of CuBr with tetrahydrothiophene (THT) in MeCN solution. The two-dimensional layers consist of two different types of rhomboid-shaped dinuclear ...
Access
Discipline
- Crystallography
- Chemistry, organic
- Materials science, multidisciplinary
- Water resources
- Chemistry, inorganic & nuclear
- Chemistry, analytical
- Chemistry, physical
- Ecology
- Physics, atomic, molecular & chemical
- Electrochemistry
- Engineering, electrical & electronic
- Energy & fuels
- Materials science, characterization & testing
- Multidisciplinary sciences
- Materials science, composites
- Microbiology
- Mathematical & computational biology
- Engineering, industrial
- Polymer science
- Engineering, environmental
- Medical informatics
- Biochemistry & molecular biology
- Biodiversity conservation
- Astronomy & astrophysics
- Physics, mathematical
- Plant sciences
- Surgery
- Nanoscience & nanotechnology
- Biology
- Biology, miscellaneous
- Biophysics
- Cell biology
- Chemistry, applied
- Computer science, artificial intelligence
- Computer science, software engineering
- Dermatology
- Engineering, chemical
- Engineering, mechanical
- Environmental sciences
- Geology
- Geosciences, multidisciplinary
- Instruments & instrumentation
- Logic
- Marine & freshwater biology
- Materials science, biomaterials
- Materials science, coatings & films
- Mathematics
- Mechanics
- Microscopy
- Mineralogy
Structure
Collection
- Single-crystal X-ray structures
- Organic synthesis
- Données de thèse
- Chimie des eaux-basse vallée de l'Ain
- Bioorganic synthesis
- Équipe SHERPAC
- Inorganic synthesis
- Hydrogène
- Données de thèse de Charles Henriot
- Elaboration des matériaux luminescents
- Pile à combustible
- Dynamique des orogènes anciennes
- Organometallic complexes with metal-metal bonds
- Lipid model membranes
- Molecular dynamics
