Synthesis of Tris(arylphosphite)-ligated Cobalt(0) Complexes [Co2(CO)6{P(OAr)3}2], and their Reactivity towards Phenylacetylene and Diphenylacetylene
The dinuclear complexes [Co2(CO)6{P(OAr)3}2] (1a, Ar = Ph; 1b, Ar = o-Tol) were prepared and reacted with PhC≡CH and PhC≡CPh to yield dimetallatetrahedranes [{(ArO)3P}(OC)2Co-Co(μ-RC≡CPh)(CO)2{P(OAr)3}] (3a, Ar = Ph, R = H; 3b, Ar = o-Tol, R = H; 3c, Ar = Ph, R = Ph; 3d, Ar = o-Tol, R = Ph). The ...
Downscaling CMIP5 climate projections over the Mont-Blanc Massif at a 200-m resolution
Statistical downscaling of outputs (daily minimum and maximum air temperature at 2-m) of 13 Earth System Models (simulations: HIST period 1950-2006; RCP2.6 and RCP8.5 period 2006-2100) at a 200-m resolution over and around the Mont-Blanc Massif (Western Europe, border between France and Italy and ...
Climate simulations at a kilometer scale over the Mont-Blanc
Ten-member ensemble simulations performed over the Mont-Blanc massif with the ARW/WRF regional climate model, period 1979-2012, forced by ERA-Interim reanalyses
