Control of Structures and Emission Properties of (CuI)n 2-Methyldithiane Coordination Polymers
A structurally unique and strongly luminescent nonporous 3D coordination polymer (CP) [Cu8I8(methyldithiane)4]n, CP3, has been prepared in a quasi-anticipated manner from 2-methyl-1,3-dithiane, L1, and CuI. This CP incorporates an unprecedented Cu8I8 cluster built upon two side-fused open cubanes. ...
A Fused Poly(truncated rhombic dodecahedron)-Containing 3D Coordination Polymer: A Multifunctional Material with Exceptional Properties
The design of new and inexpensive metal-containing functional materials is of great interest. Herein is reported a unique thermochromic near-IR emitting coordination polymer, 3D-[Cu8I8(L1)2]n, CP2, which is formed when ArS(CH2)4SAr (L1, Ar = 4-C6H4OMe) reacts with 2 equiv of CuI in EtCN. In MeCN, ...
Downscaling CMIP5 climate projections over the Mont-Blanc Massif at a 200-m resolution
Statistical downscaling of outputs (daily minimum and maximum air temperature at 2-m) of 13 Earth System Models (simulations: HIST period 1950-2006; RCP2.6 and RCP8.5 period 2006-2100) at a 200-m resolution over and around the Mont-Blanc Massif (Western Europe, border between France and Italy and ...
Climate simulations at a kilometer scale over the Mont-Blanc
Ten-member ensemble simulations performed over the Mont-Blanc massif with the ARW/WRF regional climate model, period 1979-2012, forced by ERA-Interim reanalyses