Synthesis of Tris(arylphosphite)-ligated Cobalt(0) Complexes [Co2(CO)6{P(OAr)3}2], and their Reactivity towards Phenylacetylene and Diphenylacetylene
Disciplines :
crystallography
Collected date : from 2018 to 2020
The dinuclear complexes [Co2(CO)6{P(OAr)3}2] (1a, Ar = Ph; 1b, Ar = o-Tol) were prepared and reacted with PhC≡CH and PhC≡CPh to yield dimetallatetrahedranes [{(ArO)3P}(OC)2Co-Co(μ-RC≡CPh)(CO)2{P(OAr)3}] (3a, Ar = Ph, R = H; 3b, Ar = o-Tol, R = H; 3c, Ar = Ph, R = Ph; 3d, Ar = o-Tol, R = Ph). The ...
Regional desert dust and climate modeling in North Equatorial Africa : a 21-year WRF-CHIMERE simulation exercise
Disciplines :
physics, atomic, molecular & chemical
environmental sciences
meteorology & atmospheric sciences
Collected date : from Apr 1993 to Apr 2014
Creators :
Nadège Martiny
Pascal Roucou
CHIMERE is a chemistry-transport model recently implemented in our laboratory. CHIMERE is able to model all kind of gaseous and aerosol species, the version used here being specifically adapted to simulate the emissions, transport and deposition of desert dust. We used two nested domains, namely ...