Bis{(4-methylthio)phenylthio}methane as assembling ligand for the construction of Cu(I) and Hg(II) coordination polymers. Crystal structures and topological (AIM) analysis of the bonding
The novel 1D coordination polymer (CP) [{Cu(μ2-Br)2Cu}(μ-L2)2] CP2 has been obtained by reaction of the tetrakisthioether p-MeSC6H4SCH2SC6H4SMe-p (L2) with CuBr in a 1:2 metal-to ligand ratio. In contrast to the previously described CP [{Cu(μ2-Br)2Cu}(μ-L1)2] CP1 obtained by reaction of the ...
2-(2,2-Dibromoethenyl)thiophene
The title compound, C6H4Br2S, represents a versatile building block for the preparation of [pi]-conjugated redox-active thienyl oligomers and metal-mediated cross-coupling reactions. This is due to the presence of an electrochemically active thienyl heterocycle and a reactive dibromovinyl ...
4,12-Bis(2,2-dibromovinyl)[2.2]paracyclophane
In the title compound, C20H16Br4, both vinylic substituents were introduced by a Corey-Fuchs reaction using 4,12-diformyl[2.2]paracyclophane as starting material. The title compound may be used as a valuable precursor for the synthesis of diethynyl[2.2]paracyclophane. The title molecule is ...
4,4-Bis(4-methylphenylsulfanyl)-1,1-diphenyl-2-azabuta-1,3-diene
In the title compound, C29H25NS2, both the Cl atoms of the azadiene precursor 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene are replaced by two vicinal S-p-tolyl substituents attached to the terminal C atom of a [pi]-conjugated 2-azabutadiene array. The azadiene chain is planar to within 0.01 Å. ...
(2,2-Dichlorovinyl)ferrocene
The title compound, [Fe(C5H5)(C7H5Cl2)], represents a versatile building block for the preparation of [pi]-conjugated redox-active compounds or polymetallic organometallic systems due to the presence of the electrochemically active ferrocenyl unit. It is therefore a potential starting material for ...
Crystal structure of 4,4-dibromo-1-(3,4-dimethoxyphenyl)-2-azabuta-1,3-diene-1-carbonitrile
The title compound, C12H10Br2N2O2, represents an example of a planar π-conjugated 2-azabutadiene molecule, which is both an interesting starting material for further organic transformations and a potential ligand in organometallic coordination chemistry. Its metric molecular parameters are ...
Two-dimensional polymeric [Hg4([mu]2-I)6I2([mu]2-C4S6)]n
The title compound, poly[([mu]2-2H,5H-1,3-dithiolo[4,5-d][1,3]dithiole-2,5-dithione)hexa-[mu]2-iodido-diiodidotetramercury(II)], [Hg4I8(C4S6)]n, represents the first example of a coordination polymer assembled by the [alpha],[alpha]-C4S6 dithione ligand. The HgII ions are four-coordinated in a ...
[μ-Bis(diphenylphosphanyl)methane]-tricarbonyl(μ-p-toluenesulfonylmethylisocyanato)(triphenylphosphane)iron-platinum(Fe-Pt)
The title compound, [FePt(C9H9NO2S)(C18H15P)(C25H22P2)(CO)3], represents a rare example of an isonitrile-bridged heterobimetallic complex (here Pt and Fe) and is an interesting precursor for the preparation of heterodinuclear [mu]-aminocarbyne complexes, since the basic imine-type N atom of the ...
TNO Astrometric database
Astrometric observations of TNOs obtained during the Canada-France Ecliptic Plane Survey (CFEPS), the High Latitude Survey (HiLat) and the Outer Solar System Origin Survey (OSSOS). Database also provides orbital information and dynamical classification, and future position predictions.
HydraVitis high spatial resolution hourly near ground air temperature data set, collected in a Burgundy (France) vineyard from 2014
This database collects temperature data collected at a 15 minutes time step by thermal probes (HoBo Pendant) located at 60 cm from the ground, on simple upper radiation shelters. The network is located in a wine growing region in Burgundy, around Aloxe Corton (47°04' N ; 4°51' E). 45 sensors are ...
Echinococcus multilocularis in red fox in Franche-Comte, France
Provides data on Echinococcus multilocularis adult worms in red fox (Vulpes vulpes) in Franche-Comté administrative region, eastern France. Foxes (n=615) were night shot from october to april, from winter 1996-1997 to winter 1999-2000. Parasite worm burden was quantified using sedimentation and ...
Small mammals and arsenic in Salsigne (France)
Provides data on arsenic contamination in soils, exposure and bioaccumulation in small mammals, around a former gold mine extraction site in southern France (Salsigne, Aude). Provides also biometric data. Small mammal species are Apodemus sylvaticus (204), Mus spretus (55), Chionomys nivalis (2), ...
Wildlife Ecotoxicology - Small mammals - Metaleurop Nord
This database presents morphometric (body size and mass, organ mass or size...) and ecotoxicological (concentrations of pollutants in some organs, various biomarkers) data from small mammals (voles, mice, shrews...) captured in the surroundings of a former lead and zinc smelter named Metaleurop Nord ...
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