Acetonitrile
Translations : acetonitrile, acétonitrile
Frame of reference : The IUPAC International Chemical Identifier identified by 1S/C2H3N/c1-2-3/h1H3
Crystal structure of di-[mu]-iodido-bis[bis(acetonitrile-[kappa]N)copper(I)]
Disciplines :
chemistry, inorganic & nuclear
crystallography
Collected date : 2013
The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu...Cu distance = 2.7482 (11) Å], the CuI atoms of which are further coordinated by four molecules of acetonitrile. The CuI atom has an overall distorted tetrahedral coordination environment evidenced by L-Cu-L angles (L ...
Two-dimensional polymeric [Hg4([mu]2-I)6I2([mu]2-C4S6)]n
Collected date : from 2008 to 2009
The title compound, poly[([mu]2-2H,5H-1,3-dithiolo[4,5-d][1,3]dithiole-2,5-dithione)hexa-[mu]2-iodido-diiodidotetramercury(II)], [Hg4I8(C4S6)]n, represents the first example of a coordination polymer assembled by the [alpha],[alpha]-C4S6 dithione ligand. The HgII ions are four-coordinated in a ...
