(2,2-Dichlorovinyl)ferrocene (2009)
Available
Dataset
Licence : CC BY-NC-SA doi:10.25666/DATAOSU-2016-08-23 doi:10.1107/S1600536809006102
Data creators :
Carsten Strohmann [1],
Laurent Guyard [2] [3],
Michael Knorr [2] [3],
Sébastien Clément [2] [3],
Viktoria Gessner [1]
[1] : Technische Universität Dortmund
[2] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[3] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
Description :
The title compound, [Fe(C5H5)(C7H5Cl2)], represents a versatile building block for the preparation of [pi]-conjugated redox-active compounds or polymetallic organometallic systems due to the presence of the electrochemically active ferrocenyl unit. It is therefore a potential starting material for the preperation of the corresponding alkyne. In the crystal, the alkenyl unit and the cyclopentadienide ring are almost parallel, with an angle between the best planes of only 10.6 (4)°.
Discipline :
crystallography (chemistry)
Keywords :
General metadata
Data acquisition date :
from 2008 to 2009
Data acquisition methods :
- Experimental data : Diffraction des rayons X - Synthèse organique
Language :
English (eng)
Formats :
chemical/x-cif
Audience :
University: master, Research
Publications :
- (2,2-Dichlorovinyl)ferrocene (http://journals.iucr.org/e/issues/2009/03/00/zl2181/)
Collection :
Publisher :
International Union of Crystallography
DOI and links
10.25666/DATAOSU-2016-08-23
https://dx.doi.org/doi:10.25666/DATAOSU-2016-08-23
https://search-data.ubfc.fr/FR-18008901306731-2016-08-23
Quotation
Carsten Strohmann, Laurent Guyard, Michael Knorr, Sébastien Clément, Viktoria Gessner (2009): (2,2-Dichlorovinyl)ferrocene. IUCr. doi:10.25666/DATAOSU-2016-08-23
Record created 23 Aug 2016 by Michael Knorr.
Local identifier: FR-18008901306731-2016-08-23.
