Crystal structure of tricarbon­yl([mu]-di­phenyl­phosphido-[kappa]2P:P)(methyl­diphenyl­silyl-[kappa]Si)bis(tri­phenyl­phosphane-[kappa]P)iron(II)platinum(0)(Fe-Pt) (2015)

Data creators : Ahmed Said Mohamed [1] [2], Isabelle Jourdain [1] [2], Marek M. Kubicki [3], Michael Knorr [1] [2], Yoann Rousselin [3]
[1] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[2] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
[3] : Institut de Chimie Moléculaire de l'Université de Bourgogne (UMR 6302) (Université de Bourgogne)
Description :
The title compound, [FePt(C12H10P)(C13H13Si)(C18H15P)2(CO)3]·0.5CH2Cl2, represents an example of a phosphido-bridged heterobimetallic silyl complex; these are inter­esting precursors for the coordination and activation of small unsaturated organic mol­ecules. The [mu]2-PPh2 ligand spans the iron and platinum atoms, which are connected via a metal-metal bond of 2.7738 (4) Å. In contrast to most other complexes of the [(OC)3Fe(SiR3)([mu]-PR2)PtL2] family, where the iron-bound SiR3 group is trans-arranged with respect to the [mu]2-PPh2 ligand, the SiPh2Me ligand is roughly collinear with the Fe-Pt vector [Si-Fe-Pt = 169.07 (3)°].
Disciplines :

General metadata

Data acquisition date : 2014
Data acquisition methods :
Language : English (eng)
Formats : chemical/x-cif
Audience : University: master, Research
Publications :
Record created 19 Jul 2016 by Michael Knorr.
Last modification : 23 Aug 2016.
Local identifier: FR-18008901306731-2016-07-19-02.


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