4′-(5-Methylfuran-2-yl)-2,2′:6′,2″-terpyridine: A New Ligand Obtained from a Biomass-Derived Aldehyde with Potential Application in Metal-Catalyzed Reactions (2018)
Data creators :
Jérôme Husson [1] [2],
Laurent Guyard [1] [2]
Data collector :
Jérôme Husson [1] [2],
Laurent Guyard [1] [2]
[1] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[2] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
Description :
The new ligand 4′-(5-methylfuran-2-yl)-2,2′:6′,2″-terpyridine (1) was prepared in one step from 2-acetylpyridine and 5-methylfurfural. The latter is an aldehyde that can be readily obtained from biomass. The new terpyridine molecule was characterized by 1H and 13C-NMR spectroscopy as well as by elemental analyses and HR-MS. Owing to its chelating properties, this new terpyridine molecule was tested as a ligand in a metal-catalyzed reaction: The Ni-catalyzed dimerization of benzyl bromide.
Discipline :
chemistry, organic (chemistry)
General metadata
Data acquisition date :
from 2017 to 2018
Data acquisition methods :
- Experimental data : Organic synthesis
Formats :
application/pdf, chemical/x-mdl-molfile
Audience :
University: master, Research
Publications :
- 4′-(5-Methylfuran-2-yl)-2,2′:6′,2″-terpyridine: A New Ligand Obtained from a Biomass-Derived Aldehyde with Potential Application in Metal-Catalyzed Reactions (doi:10.3390/M1032)
Collection :
Publisher :
Multidisciplinary Digital Publishing Institute
Record created 1 Oct 2021 by Jérôme Husson.
Local identifier: FR-18008901306731-2021-10-01.
