Dataset : 4′-(5-Methylfuran-2-yl)-2,2′:6′,2″-terpyridine: A New Ligand Obtained from a Biomass-Derived Aldehyde with Potential Application in Metal-Catalyzed Reactions
General metadata
Identifiers :
local : FR-18008901306731-2021-10-01
external :
doi:10.25666/DATAOSU-2021-10-01
,
doi:10.3390/M1032
Description :
The new ligand 4′-(5-methylfuran-2-yl)-2,2′:6′,2″-terpyridine (1) was prepared in one step from 2-acetylpyridine and 5-methylfurfural. The latter is an aldehyde that can be readily obtained from biomass. The new terpyridine molecule was characterized by 1H and 13C-NMR spectroscopy as well as by elemental analyses and HR-MS. Owing to its chelating properties, this new terpyridine molecule was tested as a ligand in a metal-catalyzed reaction: The Ni-catalyzed dimerization of benzyl bromide.
Discipline :
chemistry, organic (chemistry)
Keywords :
Dates :
Data acquisition : from 2017 to 2018
Data provision : 24 Nov 2018
Metadata record :
Creation : 1 Oct 2021
Audience :
University: master, Research
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Quotation
Jérôme Husson, Laurent Guyard (2018): 4′-(5-Methylfuran-2-yl)-2,2′:6′,2″-terpyridine: A New Ligand Obtained from a Biomass-Derived Aldehyde with Potential Application in Metal-Catalyzed Reactions. MDPI. doi:10.25666/DATAOSU-2021-10-01
Administrative metadata
Data creators :
Jérôme Husson [1] [2],
Laurent Guyard [1] [2]
Data collector :
Jérôme Husson [1] [2],
Laurent Guyard [1] [2]
[1] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[2] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
Publisher :
Multidisciplinary Digital Publishing Institute
Science contact :
Jérôme Husson
Access :
available
Technical metadata
Formats : application/pdf, chemical/x-mdl-molfile
Data acquisition methods :
- Experimental data : Organic synthesis
Datatype : Dataset
Publications
- 4′-(5-Methylfuran-2-yl)-2,2′:6′,2″-terpyridine: A New Ligand Obtained from a Biomass-Derived Aldehyde with Potential Application in Metal-Catalyzed Reactions (doi:10.3390/M1032)
