(2,2-Dichloro­vinyl)ferrocene (2009)

Data creators : Carsten Strohmann [1], Laurent Guyard [2] [3], Michael Knorr [2] [3], Sébastien Clément [2] [3], Viktoria Gessner [1]
[1] : Technische Universität Dortmund
[2] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[3] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
Description :
The title compound, [Fe(C5H5)(C7H5Cl2)], represents a versatile building block for the preparation of [pi]-conjugated redox-active compounds or polymetallic organometallic systems due to the presence of the electrochemically active ferrocenyl unit. It is therefore a potential starting material for the preperation of the corresponding alkyne. In the crystal, the alkenyl unit and the cyclo­penta­dienide ring are almost parallel, with an angle between the best planes of only 10.6 (4)°.
Discipline :
crystallography (chemistry)

General metadata

Data acquisition date : from 2008 to 2009
Data acquisition methods :
Language : English (eng)
Formats : chemical/x-cif
Audience : University: master, Research
Publications :
Record created 23 Aug 2016 by Michael Knorr.
Local identifier: FR-18008901306731-2016-08-23.


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Terms of use
Université de Bourgogne, Université de Franche-Comté, UTBM, AgroSup Dijon, ENSMM, BSB, Arts des Metiers