Two-dimensional polymeric [Hg4([mu]2-I)6I2([mu]2-C4S6)]n (2011)
Available
Dataset
Licence : CC BY-NC-SA doi:10.25666/DATAOSU-2016-07-22-02 doi:10.1107/S1600536811006556
Data creators :
Aurélien Hameau [1] [2],
Carsten Strohmann [3],
Fabrice Guyon [1] [2],
Michael Knorr [1] [2],
Victoria Colquhoun [3]
[1] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[2] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
[3] : Technische Universität Dortmund
Description :
The title compound, poly[([mu]2-2H,5H-1,3-dithiolo[4,5-d][1,3]dithiole-2,5-dithione)hexa-[mu]2-iodido-diiodidotetramercury(II)], [Hg4I8(C4S6)]n, represents the first example of a coordination polymer assembled by the [alpha],[alpha]-C4S6 dithione ligand. The HgII ions are four-coordinated in a distorted tetrahedral geometry, the coordination demand being satisfied either by four bridging iodide ligands or by three iodide ligands (one terminal and two bridging) and a thiocarbonyl S atom. Due to the bridging nature of the dithione ligand, the coordination polymer has a two-dimensional structure, built up of undulated layers parallel to (001). There is an inversion center at the mid-point of the central C=C double bond.
Disciplines :
chemistry, inorganic & nuclear (chemistry), crystallography (chemistry), polymer science (chemistry)
General metadata
Data acquisition date :
from 2008 to 2009
Data acquisition methods :
- Experimental data : Diffraction des rayons X
Language :
English (eng)
Formats :
chemical/x-cif
Audience :
University: master, Research
Publications :
- Two-dimensional polymeric [Hg4([mu]2-I)6I2([mu]2-C4S6)]n (doi:10.1107/S1600536811006556)
Collection :
Publisher :
International Union of Crystallography
Record created 22 Jul 2016 by Michael Knorr.
Local identifier: FR-18008901306731-2016-07-22-02.
