Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular Cu4I4S4 and Cu8I8S6 Clusters to Luminescent Copper(I) Coordination Polymers (2015)
Data creators :
Abderrahim Khatyr [1] [2],
Antoine Bonnot [3],
Antony Lapprand [1] [2],
Carsten Strohmann [4],
Marek M. Kubicki [5],
Michael Knorr [1] [2],
Pierre D. Harvey [3],
Yoann Rousselin [5]
[1] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[2] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
[3] : Départment de Chimie - Université de Sherbrooke
[4] : Technische Universität Dortmund
[5] : Institut de Chimie Moléculaire de l'Université de Bourgogne (UMR 6302) (Université de Bourgogne)
Description :
The CuX salts (X = I, Br) react with SR2 to form molecular clusters of the types [(R2S)4(Cu4I4)] and [(R2S)6(Cu8I8)] or to give 1D polymers and 2D metal−organic frameworks. The cluster nuclearity and connectivity as well as the dimensionality of these compounds depend on the steric demand of SR2, the solvent polarity, and the nature of the halide. These materials have been characterized by X-ray and thermogravimetric analysis and steady-state and time-resolved absorption and emission spectroscopy at 298 and 77 K.
Disciplines :
chemistry, organic (chemistry), chemistry, physical (chemistry), crystallography (chemistry), materials science, characterization & testing (chemistry)
General metadata
Data acquisition date :
from 2010 to 2014
Data acquisition methods :
- Experimental data : Diffraction des rayons X. Mesures photophysiques.
- Simulation or computational data : Calculs DFT (Density Functional Theory)
Language :
English (eng)
Formats :
application/pdf, chemical/x-cif
Audience :
University: master, Research
Publications :
- Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular Cu4I4S4 and Cu8I8S6 Clusters to Luminescent Copper(I) Coordination Polymers (doi:10.1021/acs.inorgchem.5b00327)
Collection :
Publisher :
American Chemical Society
Record created 20 Jul 2016 by Michael Knorr.
Last modification : 23 Aug 2016.
Local identifier: FR-18008901306731-2016-07-20.
