Dataset : Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular Cu4I4S4 and Cu8I8S6 Clusters to Luminescent Copper(I) Coordination Polymers

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General metadata

Identifiers :
local : FR-18008901306731-2016-07-20 external : doi:10.25666/DATAOSU-2016-07-20
Description :
The CuX salts (X = I, Br) react with SR2 to form molecular clusters of the types [(R2S)4(Cu4I4)] and [(R2S)6(Cu8I8)] or to give 1D polymers and 2D metal−organic frameworks. The cluster nuclearity and connectivity as well as the dimensionality of these compounds depend on the steric demand of SR2, the solvent polarity, and the nature of the halide. These materials have been characterized by X-ray and thermogravimetric analysis and steady-state and time-resolved absorption and emission spectroscopy at 298 and 77 K.
Disciplines :
Keywords :

Dates :
Data acquisition : from 2010 to 2014
Data provision : 6 Apr 2015
Metadata record : Creation : 20 Jul 2016 Update : 23 Aug 2016

Language : English (eng)
Audience : University: master, Research
RightsAttribution, Non Commercial, Share Alike
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Collection

Quotation

Abderrahim Khatyr, Antoine Bonnot, Antony Lapprand, Carsten Strohmann, Marek M. Kubicki, Michael Knorr, Pierre D. Harvey, Yoann Rousselin (2015): Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular Cu4I4S4 and Cu8I8S6 Clusters to Luminescent Copper(I) Coordination Polymers. ACS. doi:10.25666/DATAOSU-2016-07-20

Administrative metadata

Data creators : Abderrahim Khatyr [1] [2], Antoine Bonnot [3], Antony Lapprand [1] [2], Carsten Strohmann [4], Marek M. Kubicki [5], Michael Knorr [1] [2], Pierre D. Harvey [3], Yoann Rousselin [5]
[1] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[2] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
[3] : Départment de Chimie - Université de Sherbrooke
[4] : Technische Universität Dortmund
[5] : Institut de Chimie Moléculaire de l'Université de Bourgogne (UMR 6302) (Université de Bourgogne)
Publisher : American Chemical Society
Science contact : Michael Knorr website e-mail
Access : available

Technical metadata

Formats : application/pdf, chemical/x-cif
Data acquisition methods :
Datatype : Dataset

Publications

  • Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular Cu4I4S4 and Cu8I8S6 Clusters to Luminescent Copper(I) Coordination Polymers (doi:10.1021/acs.inorgchem.5b00327)

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Université de Bourgogne, Université de Franche-Comté, UTBM, AgroSup Dijon, ENSMM, BSB, Arts des Metiers