Dataset : Crystal structure of di-[mu]-iodido-bis­[bis(aceto­nitrile-[kappa]N)copper(I)]


General metadata

Identifiers :
local : FR-18008901306731-2016-07-19 external : doi:10.25666/DATAOSU-2016-07-19 , ccdc:1427944 , doi:10.1107/S2056989015018149
Description :
The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu...Cu distance = 2.7482 (11) Å], the CuI atoms of which are further coordinated by four mol­ecules of aceto­nitrile. The CuI atom has an overall distorted tetra­hedral coordination environment evidenced by L-Cu-L angles (L = N or I) ranging from 100.47 (10) to 117.06 (2)°. The coordination geometries of the aceto­nitrile ligands deviate slightly from linearity as shown by Cu-N-C angles of 167.0 (2) and 172.7 (2)°. In the crystal, there are no significant hydrogen-bonding inter­actions present, so the crystal packing seems to be formed predominantly by van der Waals forces.
Disciplines :
Keywords :

Dates :
Data acquisition : 2013
Data provision : 1 Nov 2015
Metadata record : Creation : 19 Jul 2016 Update : 24 Sep 2021

Language : English (eng)
Audience : University: master, Research
RightsAttribution, Non Commercial, Share Alike


Eva Rebecca Barth, Christopher Golz, Michael Knorr, Carsten Strohmann (2015): Crystal structure of di-[mu]-iodido-bis­[bis(aceto­nitrile-[kappa]N)copper(I)]. IUCr. doi:10.25666/DATAOSU-2016-07-19

Administrative metadata

Data creators : Eva Rebecca Barth [1], Christopher Golz [1], Michael Knorr [2] [3], Carsten Strohmann [1]
[1] : Technische Universität Dortmund
[2] : Institut UTINAM (UMR 6213) (Université de Franche-Comté)
[3] : Observatoire des Sciences de l'Univers - Terre, Homme, Environnement, Temps, Astronomie (UAR 3245) (Université de Franche-Comté)
Publisher : International Union of Crystallography
Science contact : Michael Knorr website e-mail
Access : available

Technical metadata

Formats : chemical/x-cif
Data acquisition methods :
Datatype : Dataset



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